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- W1152423041 abstract "The catalytic effect of enzymes is based in part on their capacity to endow the substrates with highly increased chemical reactivity. This superreactivity of enzyme-activated substrates manifests itself in the increased rate of the chemical transformation of the specific substrate into the specific product; it may, however, also comprise enhanced reactivity toward extrinsic reagents that are not constituents of the normal enzyme-substrate system. Enzyme-substrate intermediates may thus react with extrinsic reagents and branch off the normal catalytic pathway. The term “paracatalytic enzyme reaction” is suggested to describe these reactions that, except in the first stages of their pathway, do not correspond with the normal catalytic specificity of the enzyme. This chapter describes the principal features of paracatalytic enzyme modification accompanying the oxidation of enzyme-substrate carbanion intermediates. It discusses its differentiation from other substratedependent and catalysis-linked modifications, and concludes with an accouat of detailed modification procedures for several enzymes." @default.
- W1152423041 created "2016-06-24" @default.
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- W1152423041 date "1977-01-01" @default.
- W1152423041 modified "2023-10-16" @default.
- W1152423041 title "[5] Paracatalytic enzyme modification by oxidation of enzyme—substrate carbanion intermediates" @default.
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- W1152423041 doi "https://doi.org/10.1016/s0076-6879(77)46009-9" @default.
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