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- W1167665890 abstract "This paper is a continuation of our work reported previously (1) on the interaction between ester solvents and alkene volatile organic compounds (VOCs). The interactions were presented inform of infinite dilution activity coefficients. A Microsoft Excel spreadsheet for the modified UNIFAC Dortmund group contribution method (2) was designed and used in computing the required phase equilibrium. The size of the solvent molecule (biodiesel) relative to the VOC molecule influenced the thermodynamic interactions. The degree of ester (biodiesel) bond saturation influenced the ease in which cyclic VOCs interacted with the solvent compared to their straight chain counterparts. The location of branches such as methyl branches in relation to the double-bonded carbons had an impact on the predicted infinite dilution activity coefficients. M. Caproate 1-C6:0 1.270 1.368 1.458 1.542 1.621 1.696 M. Laurate 1-C12:0 0.849 0.913 0.968 1.018 1.062 1.102 M. Stearate 1-C18:0 0.689 0.747 0.798 0.844 0.886 0.924 M. Oleate 1-C18:1 0.701 0.769 0.833 0.893 0.949 1.003 M. Linoleate 1-C18:2 0.719 0.800 0.879 0.956 1.031 1.106 M. Linolenate 1-C18:3 0.742 0.840 0.937 1.036 1.135 1.237 E. Stearate 2-C18:0 0.671 0.727 0.778 0.824 0.866 0.904 E. Oleate 2-C18:1 0.681 0.748 0.810 0.868 0.924 0.976 P. Stearate 3-C18:0 0.653 0.709 0.760 0.805 0.847 0.885 P. Oleate 3-C18:1 0.662 0.728 0.789 0.846 0.900 0.951 B. Stearate 4-C18:0 0.637 0.692 0.742 0.788 0.829 0.867 B. Oleate 4-C18:1 0.645 0.709 0.769 0.825 0.878 0.929 Este r" @default.
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- W1167665890 date "2012-01-01" @default.
- W1167665890 modified "2023-09-26" @default.
- W1167665890 title "Alkenes - ester polymeric solvents thermodynamic interactions - part 2" @default.
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