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• W1170434226 abstract "The complete electrical characterisation of a collection of charged particles dispersed in a fluid would require the specification of (i) the average density per unit volume of positive and negative charges in the surface layers of the particle, (ii) the disposition of balancing ions in the surrounding fluid and (iii) the dielectric structure in the region around the particle, and especially near to the particle surface where the high local electric fields are likely to induce significant changes from the value for the bulk fluid. It is conceivable that in some situations the degree of departure from the average charge distribution might also influence the observed behaviour. In practice, such detailed information is not available and we must make do with much less specific data. In particular, it is normal to assume that the particle charge is confined to its surface, that only the net charge is significant, and that it is uniformly distributed over the combined particle area. Although there is reason to believe that even the classic silver iodide sol does not conform to this ideal (see e.g. SPARNAAY (1)) it is a reasonable starting point for the treatment of most systems. An exception is the very important clay mineral kaolinite, where the hexagonal plate-like crystals carry a negative charge on the cleavage planes but, at low pH, a positive charge around the crystal edges(2)." @default.
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• W1170434226 date "1985-01-01" @default.
• W1170434226 modified "2023-10-17" @default.
• W1170434226 title "Characterization of Electrically Charged Colloidal Particles" @default.
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• W1170434226 doi "https://doi.org/10.1007/978-3-0348-6513-5_9" @default.
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