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• W1186640008 abstract "The applicability of core–shell phases in preparative separations was studied by a modeling approach. The preparative separations were optimized for two compounds having bi-Langmuir isotherms. The differential mass balance equation of chromatography was solved by the Rouchon algorithm. The results show that as the size of the core increases, larger particles can be used in separations, resulting in higher applicable flow rates, shorter cycle times. Due to the decreasing volume of porous layer, the loadability of the column dropped significantly. As a result, the productivity and economy of the separation decreases. It is shown that if it is possible to optimize the size of stationary phase particles for the given separation task, the use of core–shell phases are not beneficial. The use of core–shell phases proved to be advantageous when the goal is to build preparative column for general purposes (e.g. for purification of different products) in small scale separations." @default.
• W1186640008 created "2016-06-24" @default.
• W1186640008 creator A5007331593 @default.
• W1186640008 creator A5037619266 @default.
• W1186640008 date "2015-08-01" @default.
• W1186640008 modified "2023-10-14" @default.
• W1186640008 title "Influence of particle size and shell thickness of core–shell packing materials on optimum experimental conditions in preparative chromatography" @default.
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• W1186640008 doi "https://doi.org/10.1016/j.chroma.2015.06.037" @default.
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