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- W1188572595 abstract "Publisher Summary Henry Gilman presents some personal notes on more than one-half century of organo-metallic chemistry. Henry carried out his first organo-metallic reaction in 1912. The reaction was between acetone and methylmagnesium iodide to give tert-butyl alcohol. In the early development of organo-metallic chemistry, those organo-metallic compounds which found widest applicability for synthetic purposes were the organo-zinc and organo-mercury compounds. The picture changed dramatically with the advent of Grignard reagents. Another phase came with the organo-lithium compounds, because of their complementary and special properties which serve to set them apart from other types. The historically important organo-zinc compounds have been largely superseded for synthetic purposes by the magnesium and lithium compounds which are less inflammable, less toxic, and more conveniently manipulated. The number of comparisons among different types of organo-metallic compounds continued to accrue. Concurrently we had examined the relative reactivities of different members of a given series, as was the case with the broad class of organo-magnesium compounds." @default.
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- W1188572595 date "1969-01-01" @default.
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- W1188572595 title "Some Personal Notes on More Than One-Half Century of Organometallic Chemistry" @default.
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- W1188572595 doi "https://doi.org/10.1016/s0065-3055(08)60291-9" @default.
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