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- W1200888910 abstract "Complexes[MCl2{CH3N(CH2CH2N=CR^1R^2)2}](3,M=Co,R^1=H,R^2=Pb;4,M=Fe,R^1=H,R^2=Ph;5.M=Co,R^1=R^2=Ph)were prepared and characterized by IR spectra and elemental analysis.The combination of each of complexes 3-5 with ethylaluminoxane(EAO),respectively,was found to be moderately active for ethylene oligomerization to low carbon olefins.The activity of 113kg oligomers·mol^-1 Co·h^-1 for complex 3(100mol of EAO,180℃and 1.8MPa ethylene)was observed with a selectivity of 93% to C4-10 olefins,of which 96% were linear C4-10 olefins.The catalytic properties of complexes 3-5 were compared with those of analogous P,P-coordinated complexes[MCl2{CH3N(CH2CH2PPh2)2}](1.M=Co;2,M=Fe)." @default.
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- W1200888910 date "2003-01-01" @default.
- W1200888910 modified "2023-09-28" @default.
- W1200888910 title "Catalytic Effect of Cobalt and Iron Complexes Incorporating Bis（2—aldiminoethy1）amine Ligands on Ethylene Oligomerization" @default.
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