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- W1206339979 abstract "Au cours d'essais de cyclisation électrophile. le chlorure d'o-phényl telluro benzoyle ne se cyclise pas en telluroxanthone. mais s'isomérise en halogénure de tellurényle. l'o-chlorotelluro benzophénone. due a une carbodételluration intramoléculaire. Une coupure de la même liaison Caromatique-tellure se réalise aussi par protonolyse. Cette dernière réaction conduit à une méthode préparative de synthèse de l'acide ditellurosalicylique, base de nombreux hétérocycles tellurés benzocondensés. In the course of electrophilic cyclisation attempts, o-phenyltellurobenzoyl-chloride did not cyclise to telluroxanthone. but isomerised to 2-chloro tellurobenzophenone through intramolecular carbodetelluration. A breaking of the same Caromatic-Te bond is also realized by protonolysis. This last reaction leads to a preparative method of synthesis of ditellurosalicylic acid, a starting material for synthesis of benzocondensed tellurium heterocycles." @default.
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- W1206339979 date "1978-01-01" @default.
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- W1206339979 title "Halogenures de tellurenyle—iii" @default.
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- W1206339979 doi "https://doi.org/10.1016/0040-4020(78)88100-9" @default.
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