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- W121854147 abstract "The photolysis at 254 nm of perfluoroacetyl fluoride (CF3COF) in the gas phase yields C2F6, CF2O and CO as products. An excess of O2 added to the system leads to the formation of CF2O and CO2 as main products. If, instead of O2, c-C6H12 were added, the main products are CF3H and HC(O)F. In both cases a faster rate of CF3COF dissapearance is observed. The measurement of the quantum yield for CF3COF consumption as well as for products formation are: for CF3COF alone, φCF3COF=2φC2F6=2φCF2O=0.43±0.05; in the presence of c-C6H12 φCF3COF=φCF3H = 1.02 ± 0.02 and in the presence of O2, φCF3COF=1.02±0.05. The low quantum yield observed for pure CF3COF suggests the occurence of the recombination reaction:CF3+FCO→CF3COFfor which we calculated the rate constant as (6.9 ± 0.8) × 10−12 cm3 molecule−1 s−1." @default.
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- W121854147 date "1999-03-01" @default.
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- W121854147 title "Photochemistry of perfluoroacetyl fluoride" @default.
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- W121854147 doi "https://doi.org/10.1016/s1010-6030(98)00431-6" @default.
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