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- W123403782 abstract "This chapter discusses the Raman effect which results from the interaction of vibrational and rotational motions of molecules with electromagnetic radiation. Brillouin scattering involves the translational motion of molecules in liquids and solids. A simple classical picture of the Raman effect can be obtained by analogy with the amplitude modulation of a radiofrequency carrier wave by an audio signal. The resulting sidebands are similar to the Raman spectrum produced by the combination of the frequencies of molecular vibrations with the frequency of the laser excitation. However, for most purposes, a quantum mechanical model is more useful. The interaction of a molecule with electromagnetic radiation can thus be analyzed in terms of an energy-transfer mechanism. The simplest absorption process involves the gain of a quantum of energy by the molecule, accompanied by the annihilation of a quantum of light or photon. Similarly, spontaneous emission can be described as the creation of one or more photons due to the corresponding loss in molecular energy. The “excitation profile” in resonance Raman spectroscopy describes the intensity of Raman scattering as a function of the frequency of the excitation." @default.
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- W123403782 date "1996-01-01" @default.
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- W123403782 title "The Raman Effect" @default.
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- W123403782 doi "https://doi.org/10.1016/b978-012189690-4/50021-1" @default.
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