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- W123485113 abstract "Chemical phenomena are controlled by natural forces and relativity effects. Coulombic and magnetic forces are two types of conflicting forces that must be balanced in any chemical systems. Their interplay leads to diverse chemical phenomena such as anti-aromaticity, stereoselectivity of electrocyclisation reactions, and the periodic table of elements. The magnetic force due to the orbital angular momentum along the ring of a delocalized cyclic organic species is discussed in this paper as one of the control factors in organic chemistry. The most stable state (e.g. aromatic species and the noble gases) can be reached when the interference of these two types of forces reaches a minimum in a closed-shell setting. A strong interference of the two forces can be seen in an unstable antiaromatic species. Like the conjugated π-systems of aromatic compounds, the transition state of a thermally concerted cycloaddition is a strictly closed-shell species of minimum magnetic interference. A thermal chemical reaction favors a closed-shell pathway in which the conflict between the Coulombic forces and magnetic forces is minimized. The interpretation of physical laws on forces in chemistry could lead to a more uniformed understanding of physical sciences." @default.
- W123485113 created "2016-06-24" @default.
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- W123485113 date "2002-10-01" @default.
- W123485113 modified "2023-09-27" @default.
- W123485113 title "Natural Forces as the Foundation of Theoretical Explanations in Organic Chemistry" @default.
- W123485113 hasPublicationYear "2002" @default.
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