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- W12353453 abstract "Most of the “increased-valence” structures that we have discussed so far may be derived from Lewis structures by delocalizing lone-pair ( uppi ) and/or ( {overline{uppi }} ) electrons into vacant bonding or antibonding orbitals. The atomic orbital overlaps that are appropriate for some of these delocalizations are shown in Figs. 1-5 and 2-4. We shall now consider a few systems whose “increased-valence” structures can be constructed by delocalizing one or more lone-pair σ electrons of a Lewis structure into bonding or antibonding σ orbitals. Some other examples will also be discussed in Chapter 20, where the theory will be presented in a slightly different form. However, the principles for both chapters are the same." @default.
- W12353453 created "2016-06-24" @default.
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- W12353453 date "2015-10-31" @default.
- W12353453 modified "2023-09-27" @default.
- W12353453 title "Some Electron-Excess σ Bonded Systems" @default.
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- W12353453 doi "https://doi.org/10.1007/978-3-319-16676-6_19" @default.
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