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• W123661935 abstract "ABSTRACT Hydrodynamic chromatography (HDC) is a method developed by Small (1) for the measurement of the particle sizes of colloidal sols. The diluted colloidal sol is injected into an eluant stream, which is pumped through a series of beds packed with solid spheres. The larger colloidal particles pass through the beds faster than the smaller particles, and the separation achieved is detected turbidimetrically. This paper describes a mathematical model of the flow dynamics of the colloidal particles within the packed beds. This model is based on the analysis of flow of colloidal particles through a collection of equal-size parallel capillaries which are connected in series by mixing regions. The model takes into account the disturbance of the eluant flow profile by the particles and the forces (electrostatic repulsion and London-van der Waals attraction) between the colloidal particles and the bed packing. The predictions of the model are in excellent agreement with data for monodisperse polystyrene latexes reported by Small (1) and obtained in our laboratory, except for large particles and eluants of low ionic strength. The reasons for these discrepancies are outlined." @default.
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• W123661935 date "1976-01-01" @default.
• W123661935 modified "2023-09-28" @default.
• W123661935 title "HYDRODYNAMIC CHROMATOGRAPHY OF LATEX PARTICLES" @default.
• W123661935 cites W1965771888 @default.
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• W123661935 doi "https://doi.org/10.1016/b978-0-12-404504-0.50058-7" @default.
• W123661935 hasPublicationYear "1976" @default.
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