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- W125023274 abstract "The well known title compound, trans -[Mo(C 18 H 15 P) 2 (CO) 4 ], has not been studied previously by X-ray crystallography, unlike its cis isomer. The complex possesses crystallographically imposed inversion symmetry, with the Mo atom residing on an inversion centre (1 a Wyckoff position). The two triphenylphosphane groups are arranged in a staggered orientation. Each of the phenyl groups exhibits significantly different Mo—P—C—C torsion angles ranging from 2.6 (2) to 179.4 (1)°, most likely due to steric interactions based upon their positions relative to the carbonyl ligands." @default.
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- W125023274 date "2014-01-11" @default.
- W125023274 modified "2023-09-27" @default.
- W125023274 title "<i>trans</i>-Tetracarbonylbis(triphenylphosphane-κ<i>P</i>)molybdenum(0)" @default.
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- W125023274 doi "https://doi.org/10.1107/s1600536814000300" @default.
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