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• W125452486 abstract "Chiral bifunctional rhodium complexes bearing chiral bis(oxazolinyl)phenyl ligand (phebox) catalyzed asymmetric reactions were described. Meridional C 2-symmetric environment around the metal center in the chiral phebox ligand is a crucial structure factor for determining the catalytic performance in terms of reactivity and selectivity. The phebox–Rh chloro complex serves as a mild Lewis acid catalyst for asymmetric allylation, hetero-Diels–Alder, and Michael reaction. Although the catalytic precursor, Rh(III) complex, with octahedral geometry is a quite stable molecule, it can be readily activated by hydrosilane to generate the putative Rh(I) species, which is a key intermediate in asymmetric hydrosilylation of alkenes and conjugate reduction of α,β-unsaturated carbonyl compounds. The Rh enolate species generated in situ can be used for the C–C bond formation reaction, asymmetric reductive aldol reactions, and direct aldol reactions." @default.
• W125452486 created "2016-06-24" @default.
• W125452486 creator A5009287865 @default.
• W125452486 creator A5077559548 @default.
• W125452486 date "2011-01-01" @default.
• W125452486 modified "2023-10-12" @default.
• W125452486 title "Bifunctional Phebox Complexes for Asymmetric Catalysis" @default.
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• W125452486 doi "https://doi.org/10.1007/3418_2011_5" @default.
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