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- W125555764 abstract "Experiments were undertaken for deriving equations which express alkane radiolysis yield balance and for determining the composition of various fractions. Caltulations were made of the yields of heavy residue (which does not render itself easily to experimental determination) and n-heptane in linear and non- linear regions, illustrating the utilization of composed ratios. Hydrogen, monolefins, and alkanes of normal and isomeric structure and various molecular weights were the basic products. Separate linear and non-linear radiolysis was carried out considering the initial region without secondary reactions of the products, to be linear. Radiolysis n-heptane in the non-linear region was obtained on the basis of derived ratios. The yields of the linear region, in molecules per 100 molecules of converted n-heptane at doses of 650 mrad are tabuinted. Correlations and analysis of the data show that with increased dose the hydrogen yield is close to linear, while the non-linearity of other components is considerable; the yield of heavy residue is reduced while the yield of non-saturated hydrocarbons is sharply increased, attesting to the non- saturation of the heavy residue in the non-linear region. The mean molecular weight of the yield is reduced with increased radiolysis. (R.V.J.)" @default.
- W125555764 created "2016-06-24" @default.
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- W125555764 date "1960-04-21" @default.
- W125555764 modified "2023-09-26" @default.
- W125555764 title "CALCULATION OF THE YIELDS OF ALKANE RADIOLYSIS PRODUCTS" @default.
- W125555764 hasPublicationYear "1960" @default.
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