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- W12590143 abstract "This chapter is a review of research on the hydrothermal oxidation of powdered and bulk Ti 3 SiC 2 . The interaction of Ti 3 SiC 2 powders with H 2 O was investigated at 500–700 °C under a hydrostatic pressure of 50 MPa. During hydrothermal oxidation, titanium and silicon were selectively oxidized and extracted from Ti 3 SiC 2 , resulting in the formation of TiO 2 , SiO 2 and disordered carbon, and this was attributed to the weak bonding between Ti–Si atomic layers and the layered structure of the matrices. Studies on Ti 3 Si 0.9 Al 0.1 C 2 powders demonstrated that this hydrothermal oxidation was influenced by aluminum dopant, which delayed the phase transformation from anatase to rutile, and promoted the formation of carbon, the crystallization of silica and decomposition of the matrix. Hydrothermal oxidation of bulk Ti 3 SiC 2 was investigated at 500 to 700 °C under a hydrostatic pressure of 35 MPa in continuous water flow, which obeyed a linear time-law. The oxidation was limited at 500–600 °C and accelerated at 700 °C due to the formation of cracks in oxides. Owing to the high solubility of silica in hydrothermal water, the resulting oxide layers only consisted of titanium oxides and carbon." @default.
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- W12590143 date "2012-01-01" @default.
- W12590143 modified "2023-09-22" @default.
- W12590143 title "Hydrothermal oxidation of Ti 3 SiC 2" @default.
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- W12590143 doi "https://doi.org/10.1533/9780857096012.323" @default.
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