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- W1259500 endingPage "149" @default.
- W1259500 startingPage "119" @default.
- W1259500 abstract "The synthetic versatility of α,β-unsaturated carbonyl compounds has resulted in the development of a wide variety of methods for their synthesis. Many such procedures rely on the construction of the basic carbon framework from simpler fragments, and are typified by reactions of the Wittig, Knoevenagel, aldol and Reformatsky type.1 To be able to introduce regioselective unsaturation into a previously established carbon skeleton is, however, an additional tool in the chemist’s armamentarium. In this review we have attempted to bring together the main literature relating to dehydrogenation methodology. No attempt has been made to include similar reactions that would generate alkynes or reactions that would result in the formation of carbon atoms doubly bonded to heteroatoms. Several of the intermediates described, and especially those involving α-selenenyl or α-thio moieties, offer the opportunity for further elaboration prior to elimination, since such species are able to stabilize adjacent carbanions.2–4 The synthetic applications arising from such intermediates are left to the ingenuity of the reader." @default.
- W1259500 created "2016-06-24" @default.
- W1259500 creator A5005582454 @default.
- W1259500 creator A5082411919 @default.
- W1259500 date "1991-01-01" @default.
- W1259500 modified "2023-09-23" @default.
- W1259500 title "Oxidation Adjacent to CX Bonds by Dehydrogenation" @default.
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