FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W126400518> ?p ?o ?g. }

• W126400518 endingPage "71" @default.
• W126400518 startingPage "55" @default.
• W126400518 abstract "Carbon dioxide has emerged as an important renewable carbon feedstock, and several processes are being investigated with the aim to minimise waste production and increase efficiency Carbon dioxide (CO2) is thermodynamically and kinetically very stable and therefore its direct use as a C-1 source poses significant challenge owing to its inertness. This chapter summarises recent developments in the chemical fixation of CO2 to valuable chemicals as well as defines the scope, potential and limitations of CO2 conversion. Currently, processes based on CO2 to methanol, urea, ethylene carbonate (EC) and dimethyl carbonate (DMC) are well developed. The chemicals derived from these molecules can be considered as indirect fixation of CO2 to various chemicals provided they are prepared from CO2. This can be a good alternative to direct fixation as these chemicals are reactive and can be converted to variety of other valuable chemicals. Direct synthesis of dimethyl carbonate, 1,3-disubstituted urea and 2-oxazolidinones/2-imidazolidinones from CO2 has limitations because of the reaction equilibrium and chemical inertness of CO2. This chapter mainly focuses on the preferred alternative and cleaner routes for their synthesis like transesterification of ethylene carbonate with methanol, transamination of ethylene carbonate with primary amine and transamination reaction of ethylene carbonate with diamines/β-amino alcohols, which are also discussed. On the other hand, CO2 is sequestered in nature as solid carbonate minerals, and these are abundant in nature in the form of mineral rocks (CaCO3). Catalytic hydrogenations of inorganic carbonates that are of significant interest for the production of fuels and chemicals, as they can be rapidly replenished by the carbonation process, are also discussed. Hence, these recent developments of phosgene-free approaches will sound to be viewed as a useful contribution for the indirect utilisation of CO2 in the synthesis of industrially important chemicals." @default.
• W126400518 created "2016-06-24" @default.
• W126400518 creator A5006659592 @default.
• W126400518 creator A5066517827 @default.
• W126400518 creator A5079562283 @default.
• W126400518 creator A5090644514 @default.
• W126400518 date "2014-01-01" @default.
• W126400518 modified "2023-10-12" @default.
• W126400518 title "Indirect Utilisation of Carbon Dioxide in Organic Synthesis for Valuable Chemicals" @default.
• W126400518 cites W117446292 @default.
• W126400518 cites W148139705 @default.
• W126400518 cites W1529682642 @default.
• W126400518 cites W1596679767 @default.
• W126400518 cites W1600691678 @default.
• W126400518 cites W181191598 @default.
• W126400518 cites W1967383294 @default.
• W126400518 cites W1972286662 @default.
• W126400518 cites W1973187203 @default.
• W126400518 cites W1975345633 @default.
• W126400518 cites W1975506590 @default.
• W126400518 cites W1976151767 @default.
• W126400518 cites W1978514689 @default.
• W126400518 cites W1979125190 @default.
• W126400518 cites W1980583136 @default.
• W126400518 cites W1982159630 @default.
• W126400518 cites W1984155970 @default.
• W126400518 cites W1985747091 @default.
• W126400518 cites W1986635424 @default.
• W126400518 cites W1987037160 @default.
• W126400518 cites W1988842400 @default.
• W126400518 cites W1990754239 @default.
• W126400518 cites W1991923613 @default.
• W126400518 cites W1994837034 @default.
• W126400518 cites W1995019240 @default.
• W126400518 cites W1996830598 @default.
• W126400518 cites W1997543115 @default.
• W126400518 cites W2001766927 @default.
• W126400518 cites W2007841389 @default.
• W126400518 cites W2008872937 @default.
• W126400518 cites W2009249334 @default.
• W126400518 cites W2010197901 @default.
• W126400518 cites W2016553808 @default.
• W126400518 cites W2016915412 @default.
• W126400518 cites W2017179093 @default.
• W126400518 cites W2020078456 @default.
• W126400518 cites W2020561818 @default.
• W126400518 cites W2024790059 @default.
• W126400518 cites W2025301345 @default.
• W126400518 cites W2029096543 @default.
• W126400518 cites W2029862367 @default.
• W126400518 cites W2031693207 @default.
• W126400518 cites W2031958154 @default.
• W126400518 cites W2038119766 @default.
• W126400518 cites W2038436335 @default.
• W126400518 cites W2039358663 @default.
• W126400518 cites W2041474478 @default.
• W126400518 cites W2043088618 @default.
• W126400518 cites W2043641174 @default.
• W126400518 cites W2047074808 @default.
• W126400518 cites W2048745769 @default.
• W126400518 cites W2051299738 @default.
• W126400518 cites W2052372922 @default.
• W126400518 cites W2053554182 @default.
• W126400518 cites W2054696196 @default.
• W126400518 cites W2054947576 @default.
• W126400518 cites W2055794767 @default.
• W126400518 cites W2056692747 @default.
• W126400518 cites W2063515836 @default.
• W126400518 cites W2064549353 @default.
• W126400518 cites W2066175575 @default.
• W126400518 cites W2066605766 @default.
• W126400518 cites W2069826598 @default.
• W126400518 cites W2072533896 @default.
• W126400518 cites W2072776589 @default.
• W126400518 cites W2073906977 @default.
• W126400518 cites W2074932142 @default.
• W126400518 cites W2078527804 @default.
• W126400518 cites W2078960227 @default.
• W126400518 cites W2079481228 @default.
• W126400518 cites W2081411123 @default.
• W126400518 cites W2082977937 @default.
• W126400518 cites W2087599033 @default.
• W126400518 cites W2088702264 @default.
• W126400518 cites W2091467710 @default.
• W126400518 cites W2091680897 @default.
• W126400518 cites W2092042481 @default.
• W126400518 cites W2092341996 @default.
• W126400518 cites W2092993934 @default.
• W126400518 cites W2097805256 @default.
• W126400518 cites W2098038251 @default.
• W126400518 cites W2103957666 @default.
• W126400518 cites W2105565769 @default.
• W126400518 cites W2109782609 @default.
• W126400518 cites W2110154495 @default.
• W126400518 cites W2119598915 @default.
• W126400518 cites W2125517342 @default.
• W126400518 cites W2129596503 @default.
• W126400518 cites W2152723580 @default.

• next