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- W1279345314 abstract "We have established a method to synthesize perfluorinated meso-phenylporphyrins with one phenyl group bearing a substituent in the ortho position. These novel electron-deficient porphyrins are interesting for model enzymes, catalysis, photodynamic therapy, and electron transfer. The key step is the synthesis of an iodine-substituted porphyrin and its Suzuki cross coupling with boronic acid derivatives. We applied the novel strategy to synthesize a highly electron-deficient, azopyridine-substituted Ni-porphyrin that undergoes an improved ligand-driven coordination-induced spin-state switch." @default.
- W1279345314 created "2016-06-24" @default.
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- W1279345314 date "2015-08-25" @default.
- W1279345314 modified "2023-09-27" @default.
- W1279345314 title "Synthesis of Functionalized Perfluorinated Porphyrins for Improved Spin Switching" @default.
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- W1279345314 doi "https://doi.org/10.1021/acs.joc.5b01524" @default.
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