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• W128207625 abstract "In this paper results are presented on the reduction of nitrobenzene which was first investigated by Haber who pointed out the usefulness of working at constant potential. The oxidation and reduction of intermediates formed in the reaction have also been studied. The form of the relation between current and the potential of the working electrode is interpreted and the concentration and pH dependence of the reaction rates is examined in different regions. It is shown that simple kinetic laws govern the reduction processes under some conditions and the role of the solvent in affecting the reduction is emphasized. Quantitative reductions can be carried out in many cases and these results show that the reduction scheme proposed by Haber must be modified in some respects. The detailed kinetic scheme suggests that the products of electrolysis can be changed by pulsing the electrode between two different potentials for controlled lengths of time and this has been confirmed. As an example of an oxidation reaction at an electrode the kinetics of the Kolbe reaction have been examined using controlled potential pulse electrolysis. It is shown that above a certain pulse length ethane is formed by a second order reaction while for shorter pulses there is a “relaxation”, methanol being formed (and further oxidized) by a pseudo first-order process. The possibility of controlling reactions by pulse length as well as by potential height is discussed, as an example of controlling reactions by relaxation methods." @default.
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• W128207625 date "1965-01-01" @default.
• W128207625 modified "2023-10-18" @default.
• W128207625 title "THE INVESTIGATION OF THE KINETICS OF THE ELECTRODE REACTIONS OF ORGANIC COMPOUNDS BY POTENTIOSTATIC METHODS" @default.
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• W128207625 doi "https://doi.org/10.1016/b978-1-4831-9831-6.50045-x" @default.
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