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- W129313788 abstract "The association of an inactive binder with a dealuminated mordenite in a catalyst developed for the selective conversion of methanol into light olefins causes a decrease in the activity of the zeolite and an improvement of its stability. Ammonia thermodesorption and model reactions – n-heptane cracking at 803 K and metaxylene isomerization at 623 K – show that the activity decrease is due to a neutralization of the strongest protonic acid sites by exchange with the alkaline or alkaline-earth cations of the binder during the preparation of the catalyst. This neutralization is also responsible to part of the stability improvement. However this improvement is mainly due to the trapping by the binder of coke precursors with consequently a significant decrease in the amount of coke deposited on the zeolite, as shown by experiments with mechanical mixtures." @default.
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- W129313788 date "1994-01-01" @default.
- W129313788 modified "2023-09-25" @default.
- W129313788 title "Effect of the binder on the properties of a mordenite catalyst for the selective conversion of methanol into light olefins" @default.
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- W129313788 doi "https://doi.org/10.1016/s0167-2991(08)63725-8" @default.
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