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- W129876775 abstract "This thesis presents the results of some original work carried out by the author in the Chemistry Department of the University of Queensland during 1956 and 1957. The main object of this work was a study of the phenanthroline complexes of rhodium by the method of of isolation of compounds. Mono-, bio- and trio- derivatives were well characterised, in the chloro- and bromo-series, and by the correct choice of conditions each was produced from the direct reaction of phenanthroline with the appropriate ‘simple’ halide in aqueous solution. Some evidence was obtained for geometric isomers of the bio-complex, as required for the octahedral structure. In addition, preliminary studies were carried out on the reaction of phenanthroline with the thiocyanato- and sulphato-complexes, with the isolation in each case of apparently mono-derivatives; while the reaction of the calculated quantity of phenanthroline with potassium tris(oxalato) rhodate (III) gave a good yield of the tris(phenanthroline) rhodium (III) oxalate. A study was also made of the phenanthrolinium salts of the complex halides, but the hexachloro- and hexabromo- salts were not prepared.Some work on the rhodium/carbonate system showed the tris(carbonate) rhodate (III) ion to be unstable in the absence of an excess of carbonate ions. The absorption spectra of some of the complexes in the visible and ultraviolet regions wore measured." @default.
- W129876775 created "2016-06-24" @default.
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- W129876775 date "1958-01-01" @default.
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- W129876775 title "Studies in the chemistry of rhodium" @default.
- W129876775 hasPublicationYear "1958" @default.
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