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- W130006419 abstract "Abstract Preparation of modified ruthenium molecular sieves has been investigated in two steps-depositionof ruthenium and modifying of ruthenium molecular sieves in presence of ligands. As support sieve there were used two molecular sieves with large pore apertures and low acidity strength (zeolite L and APO-34). Correlation of in situ UV-VIS ruthenium deposition measurements with catalyst characterisation revealed that ruthenium deposition takes place not only through ionic exchange but also through adsorption of ruthenium hydrolysed species. Modifying of the ruthenium molecular sieves catalysts with ligands has as effect a diminution of electronic charge on metal. The experimental data indicate that the presence of ligand favours an enantioselective hydrogenation of D-fructose to D-mannitol even if the yields are not very high." @default.
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- W130006419 date "1995-01-01" @default.
- W130006419 modified "2023-09-27" @default.
- W130006419 title "Modified ruthenium exchanged zeolites for enantioselective hydrogenation" @default.
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- W130006419 doi "https://doi.org/10.1016/s0167-2991(06)81795-7" @default.
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