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• W130612557 abstract "Addition of carboxylate-containing polymeric materials to a metastable supersaturated calcium carbonate solution greatly reduced calcite crystal growth rates at constant supersaturation and pH = 8.5. Calcite crystallization rates were decreased to half their value in pure solutions by a tannic acid concentration of about 0.3 ppm (parts per million); a fulvic acid concentration of about 0.2 ppm; and a poly(acrylic acid) concentration of about 0.0175 ppm. An equation relating the calcite crystallization rate and the additive concentration follows an expression based on a Langmuir adsorption model. However, the Langmuir isotherm plot has two linear segments suggesting that these polyelectrolyte inhibitors may selectively adsorb initially at the fastest growing crystal faces. This relation between polyelectrolyte concentration and calcite growth rates implies inhibition by carboxylate-containing polymeric materials involves blockage of crystal growth sites on the calcite surface.KeywordsSalicylic AcidTannic AcidHumic SubstanceFulvic AcidCalcium CarbonateThese keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves." @default.
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• W130612557 date "2005-11-25" @default.
• W130612557 modified "2023-09-25" @default.
• W130612557 title "Kinetic Inhibition of Calcium Carbonate Crystal Growth in the Presence of Natural and Synthetic Organic Inhibitors" @default.
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• W130612557 doi "https://doi.org/10.1007/0-306-46915-4_11" @default.
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