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- W132496291 abstract "The garnet-type Li7La3Zr2O12 ceramic is a promising solid electrolyte for all-solid-state secondary lithium batteries. However, it faces the problem of lithium volatilization during sintering, which may cause low density and deterioration of ionic conductivity. In this work, the effects of sintering temperature and addition on the density as well as the lithium ion conductivity of Li7-xLa3Zr2-xTaxO12 (LLZTO, x=0.25) ceramics prepared by solid state reaction have been studied. It is found that optimization of the sintering temperature leads to a minor increase in the ceramic density, yielding an optimum ionic conductivity of 2.9×10-4 S·cm-1 at 25℃. Introduction of Li 3 PO 4 addition in an appropriate concentration can obviously increase the density, leading to an optimum ionic conductivity of 7.2×10-4 S·cm-1 at 25℃. This value is superior to the conductivity data in most recent reports on the LLZTO ceramics." @default.
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- W132496291 date "2013-01-01" @default.
- W132496291 modified "2023-09-28" @default.
- W132496291 title "Densification and lithium ion conductivity of garnet-type Li7-xLa3Zr2-xTaxO12 （x=0.25） solid electrolytes" @default.
- W132496291 hasPublicationYear "2013" @default.
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