Matches in SemOpenAlex for { <https://semopenalex.org/work/W13307840> ?p ?o ?g. }
- W13307840 endingPage "330" @default.
- W13307840 startingPage "303" @default.
- W13307840 abstract "It is well known that spontaneous deracemization or spontaneous chiral resolution occasionally occurs when racemic molecules are crystallized. However, it is not easy to believe such phenomenon will occur when forming liquid crystal phases. Spontaneous chiral domain formation is introduced, when molecules form particular liquid crystal phases. Such molecules possess no chiral carbon but may have axial chirality. However, the potential barrier between two chiral states is low enough to allow mutual transformation even at room temperature. Therefore the systems are essentially not racemic but nonchiral or achiral. First, enhanced chirality by doping chiral nematic liquid crystals with nonchiral molecules is described. Emphasis is made on ester molecules for their anomalous behavior. Second, spontaneous chiral resolution is discussed. Three examples with rod-, bent-, and disk-shaped molecules are shown to give such phenomena. Particular attention will be paid to controlling enantiomeric excess (ee). Actually, almost 100% ee was obtained by applying some external chiral stimuli. This is very noteworthy in the sense that we can create chiral molecules (chiral field) without using any chiral species." @default.
- W13307840 created "2016-06-24" @default.
- W13307840 creator A5073538173 @default.
- W13307840 date "2011-01-01" @default.
- W13307840 modified "2023-10-16" @default.
- W13307840 title "Spontaneous Achiral Symmetry Breaking in Liquid Crystalline Phases" @default.
- W13307840 cites W1962266628 @default.
- W13307840 cites W1966636094 @default.
- W13307840 cites W1971656442 @default.
- W13307840 cites W1976275344 @default.
- W13307840 cites W1977355863 @default.
- W13307840 cites W1979703810 @default.
- W13307840 cites W1979807348 @default.
- W13307840 cites W1986612770 @default.
- W13307840 cites W1991484573 @default.
- W13307840 cites W1991674785 @default.
- W13307840 cites W1992492631 @default.
- W13307840 cites W1994314451 @default.
- W13307840 cites W1995760356 @default.
- W13307840 cites W2001400116 @default.
- W13307840 cites W2002613773 @default.
- W13307840 cites W2008971567 @default.
- W13307840 cites W2013474259 @default.
- W13307840 cites W2015050475 @default.
- W13307840 cites W2019346007 @default.
- W13307840 cites W2019663610 @default.
- W13307840 cites W2024705089 @default.
- W13307840 cites W2024707611 @default.
- W13307840 cites W2026804779 @default.
- W13307840 cites W2033583689 @default.
- W13307840 cites W2042876217 @default.
- W13307840 cites W2042911835 @default.
- W13307840 cites W2044034832 @default.
- W13307840 cites W2044629025 @default.
- W13307840 cites W2044984209 @default.
- W13307840 cites W2051118642 @default.
- W13307840 cites W2052644627 @default.
- W13307840 cites W2053575288 @default.
- W13307840 cites W2053834543 @default.
- W13307840 cites W2054281896 @default.
- W13307840 cites W2054826567 @default.
- W13307840 cites W2059186403 @default.
- W13307840 cites W2060208846 @default.
- W13307840 cites W2060591203 @default.
- W13307840 cites W2061266381 @default.
- W13307840 cites W2063275339 @default.
- W13307840 cites W2066105894 @default.
- W13307840 cites W2067000382 @default.
- W13307840 cites W2068562337 @default.
- W13307840 cites W2076437045 @default.
- W13307840 cites W2084597833 @default.
- W13307840 cites W2086009586 @default.
- W13307840 cites W2089532447 @default.
- W13307840 cites W2089630357 @default.
- W13307840 cites W2104127323 @default.
- W13307840 cites W2111226817 @default.
- W13307840 cites W2111855602 @default.
- W13307840 cites W2112767456 @default.
- W13307840 cites W2119703552 @default.
- W13307840 cites W2127674704 @default.
- W13307840 cites W2140463048 @default.
- W13307840 cites W2154471419 @default.
- W13307840 cites W2156436111 @default.
- W13307840 cites W2157888874 @default.
- W13307840 cites W2163641250 @default.
- W13307840 cites W2337870266 @default.
- W13307840 cites W4237133772 @default.
- W13307840 cites W4254138173 @default.
- W13307840 cites W599159858 @default.
- W13307840 doi "https://doi.org/10.1007/128_2011_242" @default.
- W13307840 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21915774" @default.
- W13307840 hasPublicationYear "2011" @default.
- W13307840 type Work @default.
- W13307840 sameAs 13307840 @default.
- W13307840 citedByCount "80" @default.
- W13307840 countsByYear W133078402013 @default.
- W13307840 countsByYear W133078402014 @default.
- W13307840 countsByYear W133078402015 @default.
- W13307840 countsByYear W133078402016 @default.
- W13307840 countsByYear W133078402017 @default.
- W13307840 countsByYear W133078402018 @default.
- W13307840 countsByYear W133078402019 @default.
- W13307840 countsByYear W133078402020 @default.
- W13307840 countsByYear W133078402021 @default.
- W13307840 countsByYear W133078402022 @default.
- W13307840 countsByYear W133078402023 @default.
- W13307840 crossrefType "book-chapter" @default.
- W13307840 hasAuthorship W13307840A5073538173 @default.
- W13307840 hasConcept C121332964 @default.
- W13307840 hasConcept C124668440 @default.
- W13307840 hasConcept C13274807 @default.
- W13307840 hasConcept C138211643 @default.
- W13307840 hasConcept C159467904 @default.
- W13307840 hasConcept C159985019 @default.
- W13307840 hasConcept C178790620 @default.
- W13307840 hasConcept C185592680 @default.
- W13307840 hasConcept C192562407 @default.
- W13307840 hasConcept C204795200 @default.