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- W133081000 abstract "The influence of sulphur on the passivation of nickel-iron alloys was investigated. Particular attention was given to the relation between the surface composition and the electrochemical behaviour. A model of the passive film on a Ni/Fe alloy is suggested. The main result regarding the role of sulphur is the impossibility for the passive film to be formed when the surface is covered by a monolayer of adsorbed sulphur. The involved mechanisms, i.e. blocking and dilution effects on the adsorption of hydroxyl groups, are discussed. On sulphur-containing nickel-iron alloys, sulphur segregates on the surface during the dissolution of the metallic elements. Above a critical sulphur content a non-protective thin sulphide film is formed on the surface instead of the oxide passive film." @default.
- W133081000 created "2016-06-24" @default.
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- W133081000 date "1983-01-01" @default.
- W133081000 modified "2023-09-26" @default.
- W133081000 title "PASSIVATION OF NICKEL - IRON ALLOYS. INFLUENCE OF SULPHUR" @default.
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- W133081000 doi "https://doi.org/10.1016/b978-0-444-42252-1.50025-4" @default.
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