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- W133245593 abstract "An attempt was made to implement a generalised 5-parameter cubic equation of state into the layer structure theory (MLST) model for the study of vapour-liquid equilibrium and the adsorption of sub-critical pure fluid on non-porous graphitized thermal carbon black and micro-porous activated carbon. In this model, the fluid is viewed as a set of parallel layers, hence the name molecular layer structure. The key to the model is that the energetic component of each layer is separated into two contributions. One is due to the interaction potential of the molecules of that layer with all other layers. The other is the intra-layer Helmholtz free energy, which account for the internal energy and the entropy of that layer. The latter contribution can be readily evaluated using an equation of state. Excellent overall predictive results for the surface tension of nitrogen, argon, krypton, methane, methanol, ethane, ethylene, propane, isobutane, n-butane, n-hexane, benzene and SF6 were achieved using this model. The recurring pattern of over-predicting the surface tension values at high temperatures suggested that the interaction potential well depth, (eff/kB) is dependent on temperature. The model was then used in the study of the adsorption on non-porous graphitized thermal carbon black and micro-porous carbon with good success. The model was able to satisfactorily predict the isotherms of argon, nitrogen, ethane, ethylene, propane, SF6, n-hexane and benzene on non-porous graphitized thermal carbon black. Encouraging results also achieved for the case of adsorption on micro-porous activated carbon." @default.
- W133245593 created "2016-06-24" @default.
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- W133245593 date "2003-01-01" @default.
- W133245593 modified "2023-09-27" @default.
- W133245593 title "Modelling of vapour-liquid phase equilibrium and adsorptions on non-porous and porous carbon" @default.
- W133245593 hasPublicationYear "2003" @default.
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