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- W134155246 abstract "This chapter discusses formation of organometallic compounds and transition metal clusters. Organometallic chemistry is a rather loose label covering both the chemistry done by organic chemists where a metal is present in some apparently incidental role, such as being the template for the organic reaction, and the chemistry done by inorganic chemists usually working with transition metals and carbon based ligands. The metal-ligand bonding of organometallic compounds involves the net sharing of electrons rather than the donation and carbon is most commonly the ligating atom; one main consequence of this sharing is that the metals are almost always in the zero oxidation state in organometallic compounds. However, no clear dividing line can be drawn, for example, halogens feature in both organometallic and non-organometallic systems, and ligands with phosphorous as the ligating atom are also considered the province of the organometallic chemist. The emphasis in organometallic chemistry is on transition metal cluster compounds, which, by definition, have three or more metals bonded directly to one another. Probably the most important ligand in organometallic chemistry is CO. It forms a bridge between the transition metal complexes and the transition metal clusters. Transition metal clusters have two, more strictly three, or more metal atoms that are directly bonded to one another; therefore, not all metal electron density is available for M-L bonding. The basic problem with transition metal clusters from a theoretical standpoint is that they have too many electrons and atoms for any fundamental and rigorous theory." @default.
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- W134155246 date "1995-01-01" @default.
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- W134155246 title "Organometallic Compounds and Transition Metal Clusters" @default.
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