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- W135604003 abstract "We have prepared a series of Fe-substituted Sr 4 Mn 3− x Fe x O 10− δ strontium manganates with x =1, 3/2, and 2. These compounds adopt the n =3 Ruddlesden–Popper structure ( I 4/ mmm ), unlike the parent compound Sr 4 Mn 3 O 10 , which contains a network of face-sharing MnO 6 octahedra, with the larger Fe ion preferentially occupying the Mn/Fe (1) middle layer of the corner-sharing trioctahedra slabs. We have investigated their physical properties with X-ray diffraction, X-ray absorption near edge spectroscopy, Mössbauer spectroscopy, variable temperature resistivity, and magnetic susceptibility. In addition, for the x =2 compound we preformed room temperature neutron diffraction experiments. These compounds need to be formed at high temperatures; as a consequence they are oxygen deficient and contain some Fe 3+ . They are insulators and exhibit spin-glass-like transitions at low temperature." @default.
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- W135604003 date "2000-11-01" @default.
- W135604003 modified "2023-09-26" @default.
- W135604003 title "Properties of the n=3 Ruddlesden–Popper Phases Sr4Mn3−xFexO10−δ (x=1, 1.5, 2)" @default.
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- W135604003 doi "https://doi.org/10.1006/jssc.2000.8904" @default.
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