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- W136541966 abstract "Publisher Summary Controlling crystallization is necessary for potential applications of glassy alloys. This chapter explores the early stages of crystallization of various iron and nickel based glasses. It describes a differential thermal analysis (DTA) carried out on these alloys. To elucidate the nature of the crystallizing phase corresponding to the first stage, heat treatments of 40 K were chosen below the onset of the first peak. Because the crystallization kinetics varies with composition, DTA was also carried out after heat treatment to check whether the amplitude of the first peak was substantially reduced. The crystallization products were identified by X-ray diffraction. The microstructure and morphology were determined using electron microscopy, generally on ion-beam thinned specimens. The initial crystallization products can be separated into two classes: (1) single-phased products and (2) two-phased products. The first stage of crystallization corresponds to clear primary crystallization for TA 772, 2605 CO, 2826 MB, and YH 498. For the first two, the structure of the crystallizing phase was b.c.c. and perfect single crystals with dendritic morphology were observed. The two other glasses produced primary crystals with an f.c.c. structure. The morphology of these crystals was completely different. The crystals were oblong and contain twins. The long direction is parallel to the projection of the twin plane. There was no evidence for dendritic growth despite the fact that similar amounts of metalloids are necessarily rejected into the glassy matrix and the super cooling is similar." @default.
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- W136541966 date "1985-01-01" @default.
- W136541966 modified "2023-09-23" @default.
- W136541966 title "A COMPARATIVE STUDY OF INITIAL STAGE CRYSTALLIZATION STRUCTURES AND MORPHOLOGIES FOR SOME IRON AND NICKEL BASED GLASSY ALLOYS" @default.
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- W136541966 doi "https://doi.org/10.1016/b978-0-444-86939-5.50079-8" @default.
- W136541966 hasPublicationYear "1985" @default.
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