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- W137157783 abstract "An understanding of adsorption processes in porous materials is of fundamental importance in processes such as gas separation, catalysis and chromatography and also in the uptake and removal of molecular species in liquid media. Neutron scattering is a powerful technique which can provide direct information on the structure and dynamics of adsorbed molecules and in particular the role and influence of the adsorbent microstructure (porosity, surface characteristics) on these properties. Here the applications of several neutron scattering techniques: small angle scattering (SANS), diffraction, incoherent quasielastic and inelastic scattering (IQENS) are reviewed. These techniques have been applied in investigations of several porous systems having a controlled pore geometry: silica gels, smectite clays (montmorillonite, hectorite) and microporous carbon fibres. Particular emphasis is given to the mechanisms of adsorption of water. Here the perturbation of the intermolecular H-bond structure, resulting from molecular confinement in micropores is discussed, together with the steric orientation of water molecules in aligned samples having a highly anisotropic pore structure." @default.
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- W137157783 date "1994-01-01" @default.
- W137157783 modified "2023-09-25" @default.
- W137157783 title "Neutron Scattering Investigations Of Adsorption In Microporous Adsorbents Having Controlled Pore Geometry." @default.
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- W137157783 doi "https://doi.org/10.1016/s0167-2991(08)63083-9" @default.
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