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- W137254967 abstract "It has been found by Molecular Orbital calculations, that the energy of the LUMO of a zeolite cluster can be used to measure the softness–hardness acidity. It has been found that the higher the framework Si/AI ratio the softer is the acidity. When applied to the alkylation of aromatics, it has been calculated that the higher the framework Si/AI ratio of the zeolite, the more “orbital controlled” will be the reaction, and therefore a higher para to ortho ratio is expected. This has been confirmed experimentally during the alkylation of toluene and m–xylene by methanol on HY zeolites with different framework Si/AI ratio." @default.
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- W137254967 date "1993-01-01" @default.
- W137254967 modified "2023-10-16" @default.
- W137254967 title "SOFT AND HARD ACIDITY IN ZEOLITES AND ZEOTYPES: EVALUATION AND CATALYTIC IMPLICATIONS" @default.
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- W137254967 doi "https://doi.org/10.1016/b978-1-4832-8383-8.50130-6" @default.
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