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- W137297843 abstract "The theory of phase transitions in monomolecular polymer layers is developed as in low-dimensional systems. Two types of planar layers are considered: the layers formed by the chains lying on the surface or by the chains grafted onto it at one end. In the former case the system is two-dimensional, whereas in the latter case the chains are effectively one-dimensional. It is shown that he character of conformational transitions in these low-dimensional systems differs markedly from that of transitions in ordinary three-dimensional systems. According to the mean-field theories, the LC-ordering in a two-dimensional system of anisotropic or anisotropically interacting particles loses its jumpwise character and becomes the second-order phase transition (with the exception of a system of particles oriented along the axes of the hexagonal lattice). In a quasi-one-dimensional system of chains grafted at one end onto the surface and immersed in a solvent, the transition related to the collapse of the layer caused by a decrease in the solvent strength loses the phase character for uncharged chains, but retains the character of the first-order phase transition for polyelectrolyte chains." @default.
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- W137297843 date "2007-12-12" @default.
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- W137297843 title "Thin monomolecular polymer layers as low-dimensional polymer systems" @default.
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- W137297843 doi "https://doi.org/10.1007/bfb0114806" @default.
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