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- W137321750 abstract "Polyhalogenated hydrocarbons are known to be reduced by cytochrome P450 under hypoxic conditions. The corresponding C-radicals, the primary reaction products, may induce lipid peroxidation or may be further reduced to yield carbene complexes with cytochrome P450. In the case of polyhalogenated methanes these carbenes may hydrolyze to give CO. All other carbene complexes are also believed to be unstable especially in the presence of oxygen and have a potential activity for covalent binding to macromolecules." @default.
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- W137321750 date "1979-01-01" @default.
- W137321750 modified "2023-09-25" @default.
- W137321750 title "Carbenes and Free Radicals of Haloalkanes as Toxic Intermediates" @default.
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- W137321750 doi "https://doi.org/10.1016/b978-0-08-023199-0.50019-9" @default.
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