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- W137615237 abstract "Variable temperature magnetic susceptibility measurements have been made for Os2piv4Cl2 (piv is trimethylacetate). Electronic spectra of Os2(O2CR)4Cl2 (O2CR is piv, butyrate, acetate) in fluid solutions and CsCl pellets have been examined, and polarized single crystal spectra have been measured for Os2piv4Cl2. The measurements have been extended to liquid helium temperature for solid samples. The temperature-dependent magnetic behavior and the presence of a δ → δ* transition in the absorption spectrum near 850 nm (solution ε = 70 M−1 cm−1, z-polarized, structured in v(Os2) ∼ 220 cm−1) indicate that the ground state of these molecules is 3Eu(δ*π*). Tentative assignments have made for the z-polarized bands at 1200 nm (solution ε = 14 M−1 cm−1, structured in v(Os2) at low temperature) and 394 nm (solution ε = 11,600 M−1 cm−1) as, respectively, spin-forbidden δ* → π* and spin-allowed π(Cl) → π*(Os2) transitions. The latter assignment is supported by the observation of a large red-shift to 455 nm (solution ε= 12,600 M−1 cm−1) for the analogous band of Os2piv4Br2." @default.
- W137615237 created "2016-06-24" @default.
- W137615237 creator A5004361433 @default.
- W137615237 creator A5066801656 @default.
- W137615237 date "1997-01-01" @default.
- W137615237 modified "2023-09-23" @default.
- W137615237 title "Magnetic and spectroscopic properties of Os2(O2CR)4Cl2. Evidence for a 3(δ*π*) ground state" @default.
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- W137615237 doi "https://doi.org/10.1007/bfb0119210" @default.
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