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- W138155093 abstract "The temperature of the eutectoid reaction in the TiH system decreased at high pressures with the slope of the transformation line dTeutdP = − 0.4 ± 0.4 K kbar− 1. The line of the eutectoid reaction intersected lines of other phase equilibria in a triple point at 20.5 ± 0.5 kbar and an existence region of some high-pressure hydrogen-rich phase appeared over this pressure. Interstitial hydrogen lowered the pressure of the α to ω transition; the maximum effect amounted to about 12 kbar. Samples quenched to liquid nitrogen temperature from the region P ≳ 45 kbar, T ≳ 555 K (0.13 ⩽ x ⩽ 0.85) become superconducting with a transition temperature Tc = 4.2 K. The superconductivity is connected with the orthorhombic ϵ-phase which transformed on heating to room temperature into the face-centred tetragonal δ-phase. Structural studies under pressure indicated that some other high-pressure phases were quite likely." @default.
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- W138155093 date "1987-02-01" @default.
- W138155093 modified "2023-09-25" @default.
- W138155093 title "Phase transformations in the TiH system at high pressures" @default.
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- W138155093 doi "https://doi.org/10.1016/0022-5088(87)90036-1" @default.
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