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- W138682903 endingPage "391" @default.
- W138682903 startingPage "337" @default.
- W138682903 abstract "The formation of carbon–carbon bonds between sp3-carbons, catalyzed by transition metals, remains much less developed in comparison with the well-recognized cross-coupling reactions between unsaturated sp- and sp2-carbons until approximately a decade ago. A remarkable evolution in this field happened at the beginning of this century which was triggered by employing new ligands, including bulky alkylphosphines, di- or tri-amines, π-carbon ligands, and N-heterocyclic carbenes. These reactions can be catalyzed by Fe, Co, Ni, Pd, Cu, and Ag and constitute powerful tools in the area of synthetic chemistry for constructing carbon chains as the fundamental frameworks of organic molecules. This chapter focuses on the rapid growth of new techniques for connecting sp3-carbon centers, including stoichiometric and catalytic cross-coupling reactions of unactivated alkyl (pseudo)halides with various alkylmetals as well as reactions involving allylic and benzylic carbons. The homocoupling of alkyl halides promoted by reducing reagents and that of alkylmetals using oxidizing reagents is also discussed." @default.
- W138682903 created "2016-06-24" @default.
- W138682903 creator A5010743217 @default.
- W138682903 creator A5030550862 @default.
- W138682903 date "2014-01-01" @default.
- W138682903 modified "2023-10-09" @default.
- W138682903 title "3.07 Coupling Reactions Between sp3-Carbon Centers" @default.
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