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- W139536023 abstract "A new method of investigation of the influence of Cr(II) ions on ligand exchange in complex compounds of Cr(III), using the hanging mercury drop electrode, is proposed. This enables Cr(II) to be electrolytically generated in situ in solutions of complex compounds and the products formed to be simultaneously investigated by using voltage sweep chronoamperometry. It was found that, in the solutions containing halogen ions, by the electroreduction of [Cr(H 2 O) 6 ] 3+ , [Cr(NH 3 ) 5 H 2 O] 3+ or [Cr(NH 3 ) 5 Cl] 2+ ions and subsequent oxidation another species of Cr(III) complex ion is formed, which is reduced at a potential less negative than that of the Cr(III) complex ions present in the bulk of the solution. The intermediate species causes the occurrence of a new reduction maximum in the second cycle of the electrode polarisation. The influence of various factors such as the pH, the supporting electrolyte and the rate of voltage rise on the formation of new species was investigated. The results are discussed on the basis of Taube's hypothesis of a bridged activated complex." @default.
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- W139536023 date "1964-01-01" @default.
- W139536023 modified "2023-09-27" @default.
- W139536023 title "INVESTIGATION ON LIGAND EXCHANGE IN COMPLEX COMPOUNDS OF Cr(III) BY MEANS OF VOLTAGE SWEEP CHRONOAMPEROMETRY" @default.
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- W139536023 doi "https://doi.org/10.1016/b978-1-4832-2841-9.50087-8" @default.
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