Matches in SemOpenAlex for { <https://semopenalex.org/work/W139758314> ?p ?o ?g. }
Showing items 1 to 65 of
65
with 100 items per page.
- W139758314 abstract "RR1C(CN)- NR2R3 (R = Me or Ph, R1 = H or Me, R2 and R3 = Et or R2R,3 = piperidino), treated with Na in refluxing MePh gave, in addn. to the corresponding RR1CHNR2R3, ethylenediamine derivs., [RR1C(NR2R3)]2, which were formed by the replacement of 1 CN group by the CN-free residue of another mol. alpha -Piperidinoisobutyronitrile, m. 43-5 Deg (0.75 mole), in 250 cc. MePh added slowly to 0.75 g.-atom powd. Na in hot MePh gave 42% N-isopropylpiperidine, b15 42 Deg, and 8% 2,3-dipiperidino-2,3-dimethylbutane, b0.4 110-13 Deg. alpha -Piperidinopropionitrile, b15 92-5 Deg, gave similarly 43% 1-ethylpiperidine, b20 40 Deg, and 22% 2,3-dipiperidinobutane, b15 148-9 Deg. PhCH(CN)NEt2, b13 134-5 Deg, yielded 39% PhCH2NEt2, b16 85-7 Deg, and 45% reddish yellow [PhCH(NEt2)]2, b0.4 140 Deg." @default.
- W139758314 created "2016-06-24" @default.
- W139758314 creator A5013727307 @default.
- W139758314 creator A5022735264 @default.
- W139758314 creator A5036733779 @default.
- W139758314 date "1965-01-01" @default.
- W139758314 modified "2023-09-28" @default.
- W139758314 title "Reduction of alpha -amino nitriles with metallic sodium in toluene" @default.
- W139758314 hasPublicationYear "1965" @default.
- W139758314 type Work @default.
- W139758314 sameAs 139758314 @default.
- W139758314 citedByCount "0" @default.
- W139758314 crossrefType "journal-article" @default.
- W139758314 hasAuthorship W139758314A5013727307 @default.
- W139758314 hasAuthorship W139758314A5022735264 @default.
- W139758314 hasAuthorship W139758314A5036733779 @default.
- W139758314 hasConcept C13965031 @default.
- W139758314 hasConcept C155647269 @default.
- W139758314 hasConcept C178790620 @default.
- W139758314 hasConcept C179104552 @default.
- W139758314 hasConcept C185592680 @default.
- W139758314 hasConcept C2778142098 @default.
- W139758314 hasConcept C2780728571 @default.
- W139758314 hasConcept C537181965 @default.
- W139758314 hasConcept C544153396 @default.
- W139758314 hasConcept C71240020 @default.
- W139758314 hasConcept C8010536 @default.
- W139758314 hasConceptScore W139758314C13965031 @default.
- W139758314 hasConceptScore W139758314C155647269 @default.
- W139758314 hasConceptScore W139758314C178790620 @default.
- W139758314 hasConceptScore W139758314C179104552 @default.
- W139758314 hasConceptScore W139758314C185592680 @default.
- W139758314 hasConceptScore W139758314C2778142098 @default.
- W139758314 hasConceptScore W139758314C2780728571 @default.
- W139758314 hasConceptScore W139758314C537181965 @default.
- W139758314 hasConceptScore W139758314C544153396 @default.
- W139758314 hasConceptScore W139758314C71240020 @default.
- W139758314 hasConceptScore W139758314C8010536 @default.
- W139758314 hasLocation W1397583141 @default.
- W139758314 hasOpenAccess W139758314 @default.
- W139758314 hasPrimaryLocation W1397583141 @default.
- W139758314 hasRelatedWork W174604985 @default.
- W139758314 hasRelatedWork W196908989 @default.
- W139758314 hasRelatedWork W2226482184 @default.
- W139758314 hasRelatedWork W2233131490 @default.
- W139758314 hasRelatedWork W2402328004 @default.
- W139758314 hasRelatedWork W54745718 @default.
- W139758314 hasRelatedWork W599773668 @default.
- W139758314 hasRelatedWork W73005314 @default.
- W139758314 hasRelatedWork W848981831 @default.
- W139758314 hasRelatedWork W2483179997 @default.
- W139758314 hasRelatedWork W2507504422 @default.
- W139758314 hasRelatedWork W2827222341 @default.
- W139758314 hasRelatedWork W2831793050 @default.
- W139758314 hasRelatedWork W2840018969 @default.
- W139758314 hasRelatedWork W2843682155 @default.
- W139758314 hasRelatedWork W2850449608 @default.
- W139758314 hasRelatedWork W2853014593 @default.
- W139758314 hasRelatedWork W2853302727 @default.
- W139758314 hasRelatedWork W2861428505 @default.
- W139758314 hasRelatedWork W2876460857 @default.
- W139758314 isParatext "false" @default.
- W139758314 isRetracted "false" @default.
- W139758314 magId "139758314" @default.
- W139758314 workType "article" @default.