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- W140440170 abstract "Photoelectrolysis is a combination of a photochemical and a photoelectric process. It has in common with photochemical reactions that the storage of energy by light absorption results in a change of chemical reactivity, particularly in a variation of the redox behavior of the electronically excited system. It has in common with photoelectric devices that a separation of electric charge carriers of opposite sign is needed to convert this excitation energy into an electric current necessary for electrolysis. Systems, where the photochemical reaction occurs in the electrolyte which consequently changes its redox potential by the products of the photochemical processes, will be treated in Chapter 5. I shall, therefore, restrict my remarks to systems where the effective light absorption occurs either in the electrode or on its surface. Only a very limited number of electrode materials can be used for this purpose. Metals, the usual material for electrodes in electrolytic cells, are totally inappropriate for light energy conversion because their excited electronic states have an extremely short life time, and the energy is quickly dissipated into heat. The only electrode materials which have the property of storing light energy for a time long enough to be converted into other" @default.
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- W140440170 date "1977-01-01" @default.
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- W140440170 title "Power Generation by Photoelectrolysis" @default.
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- W140440170 doi "https://doi.org/10.1016/b978-0-12-112350-5.50010-7" @default.
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