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• W1417297170 abstract "This chapter discusses the novel types of metal–metal bonded complexes, the original synthetic pathway, the real sandwiches, and the structure, bonding, and reaction mechanism of these complexes. Binuclear sandwich-type complexes possessing a metal–metal bonded M2 unit coordinated by two planar CnHn ring systems are very rare. Among dicyclopentadienylmetal species, cobaltocene and nickelocene have been known to react under rather mild conditions. In most cases, the reaction is quite rapid at room temperature, leading to complete formation of the products in a very few minutes. Higher temperatures are only necessary with bulky ligands, such as P-i-Pr3 or PCy3 (Cy = cyclo-C6H11). The more elegant route––which is called for simplicity “the method of [1 + 1]-addition”––may also be used to prepare other binuclear complexes containing either two allyl groups or one allyl group and one halogen in the bridging positions. The two anionic species MeCOO− and 2-MeC3H4− are isostructural and isoelectronic, each contributing four electrons when coordinated as bridging ligands. A very fast rotation of the five-membered ring about the axis passing through its center and oriented perpendicular to the Pd–Pd bond takes place. The reactions of the binuclear complexes (X)(Y)M2L2 with both electrophilic and nucleophilic reagents can be divided into two categories: those in which the binuclear skeleton is retained and those in which two mononuclear products are formed. The presence of simple π-allyl and π-cyclopentadienyl ligands symmetrically coordinated to an M2 unit seems to be unique." @default.
• W1417297170 created "2016-06-24" @default.
• W1417297170 creator A5086562220 @default.
• W1417297170 date "1981-01-01" @default.
• W1417297170 modified "2023-10-16" @default.
• W1417297170 title "Novel Types of Metal-Metal Bonded Complexes Containing Allyl and Cyclopentadienyl Bridging Ligands" @default.
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• W1417297170 doi "https://doi.org/10.1016/s0065-3055(08)60366-4" @default.
• W1417297170 hasPublicationYear "1981" @default.
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