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- W14186908 abstract "Abstract Polyelectrolyte–surfactant mixtures have attracted considerable research interest in the past decades due to their widespread appearance in nature and technology. Many different systems have been studied with the purpose to identify the key features that effect their behavior and performance. In this chapter, we review our studies on polyelectrolyte–surfactant interactions in a particular system involving a strong polyelectrolyte, poly(styrenesulfonate), PSS, and oppositely charged surfactants. The interest in PSS is due to its concealed hydrophobic character related to benzene rings in its functional groups. Owing to this feature, PSS interacts strongly with oppositely charged surfactants through electrostatic and additional hydrophobic interactions, which involve solubilization of hydrophobic groups of PSS in surfactant micelles. We demonstrate that this characteristic has an important effect on binding isotherms, critical association concentration values, and free energy changes associated with the binding process, so as on the solubility and structure of the ensuing polyelectrolyte–surfactant complexes (PSCs). Good solution stability of PSCs involving PSS enabled the determination of several solution properties of soluble PSCs." @default.
- W14186908 created "2016-06-24" @default.
- W14186908 creator A5091717691 @default.
- W14186908 date "2012-01-01" @default.
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- W14186908 title "Polyelectrolytes and Surfactants in Aqueous Solutions" @default.
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- W14186908 doi "https://doi.org/10.1016/b978-0-12-396534-9.00007-6" @default.
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