Matches in SemOpenAlex for { <https://semopenalex.org/work/W1418803502> ?p ?o ?g. }
- W1418803502 endingPage "309" @default.
- W1418803502 startingPage "279" @default.
- W1418803502 abstract "This chapter discusses the developments and up-to-date review of trimethylenemethane metal complexes. Tris(carbonyl)-n4-trimethylenemethaneiron(0) was the first trimethylenemethane metal complex to be synthesized and was obtained from the reaction of 3-chloro-2-chloromethylprop-1-ene with [Fez2(CO)9] or Na2[Fe(CO)4]. The thermal extrusion of a simple molecule from an n3-allyl complex, to generate an n4-trimethylenemethane metal complex, was originally observed by Emerson. The ability of [Pd(PPh3)4] to promote the elimination of trimethylsilyl acetate from the allyl silane 31a and generate a highly reactive n3-trimethylenemethane palladium intermediate, which is considered to be of the form [Pd{n3-C(CH2)3}(PPh3)w2], was first observed by Trost and Chan. The structure of this complex has been substantiated by a single crystal X-ray study. A gas-phase electron diffraction study of tris(carbonyl)-n4-trimethylenemethaneiron establishes that the carbonyl ligands and a trigonalpyramidal trimethylenemethane ligand are in a staggered conformation about the iron with the central carbon being closer to the iron center than the outer methylene carbons. Initial studies have shown that iron trimethylenemethane complexes are susceptible to electrophilic attack. The cycloaddition of trimethylenemethane to alkenes can be envisaged as the Diels–Alder (471 + 2 π) reaction for the synthesis of five-membered rings. In the special cases of substituents that are good anion-stabilizing groups, the allyl carbonate 77 (Z = CN) serves as a suitable trimethylenemethane precursor." @default.
- W1418803502 created "2016-06-24" @default.
- W1418803502 creator A5063863419 @default.
- W1418803502 creator A5091312005 @default.
- W1418803502 date "1987-01-01" @default.
- W1418803502 modified "2023-10-14" @default.
- W1418803502 title "Trimethylenemethane Metal Complexes" @default.
- W1418803502 cites W1516314569 @default.
- W1418803502 cites W1534150946 @default.
- W1418803502 cites W1596217004 @default.
- W1418803502 cites W1814196676 @default.
- W1418803502 cites W1965633661 @default.
- W1418803502 cites W1967926030 @default.
- W1418803502 cites W1970195921 @default.
- W1418803502 cites W1970666894 @default.
- W1418803502 cites W1975532624 @default.
- W1418803502 cites W1976600524 @default.
- W1418803502 cites W1979943836 @default.
- W1418803502 cites W1983335040 @default.
- W1418803502 cites W1990229476 @default.
- W1418803502 cites W1990733318 @default.
- W1418803502 cites W1995687545 @default.
- W1418803502 cites W1998249064 @default.
- W1418803502 cites W1998622134 @default.
- W1418803502 cites W2002998657 @default.
- W1418803502 cites W2003096599 @default.
- W1418803502 cites W2003440220 @default.
- W1418803502 cites W2009981899 @default.
- W1418803502 cites W2010717137 @default.
- W1418803502 cites W2014681472 @default.
- W1418803502 cites W2017591017 @default.
- W1418803502 cites W2018738015 @default.
- W1418803502 cites W2019469062 @default.
- W1418803502 cites W2021191790 @default.
- W1418803502 cites W2023847946 @default.
- W1418803502 cites W2026205526 @default.
- W1418803502 cites W2026235187 @default.
- W1418803502 cites W2027864296 @default.
- W1418803502 cites W2031122352 @default.
- W1418803502 cites W2032307364 @default.
- W1418803502 cites W2032552267 @default.
- W1418803502 cites W2032881853 @default.
- W1418803502 cites W2035024753 @default.
- W1418803502 cites W2035251280 @default.
- W1418803502 cites W2039247956 @default.
- W1418803502 cites W2040896431 @default.
- W1418803502 cites W2040921452 @default.
- W1418803502 cites W2041342466 @default.
- W1418803502 cites W2043376047 @default.
- W1418803502 cites W2044623944 @default.
- W1418803502 cites W2050166349 @default.
- W1418803502 cites W2052115085 @default.
- W1418803502 cites W2052207597 @default.
- W1418803502 cites W2053545885 @default.
- W1418803502 cites W2053886721 @default.
- W1418803502 cites W2053930064 @default.
- W1418803502 cites W2059306840 @default.
- W1418803502 cites W2062266892 @default.
- W1418803502 cites W2065183146 @default.
- W1418803502 cites W2067825348 @default.
- W1418803502 cites W2070714044 @default.
- W1418803502 cites W2071832117 @default.
- W1418803502 cites W2072337331 @default.
- W1418803502 cites W2076464841 @default.
- W1418803502 cites W2081166464 @default.
- W1418803502 cites W2081716790 @default.
- W1418803502 cites W2085939155 @default.
- W1418803502 cites W2088989695 @default.
- W1418803502 cites W2091253368 @default.
- W1418803502 cites W2101462419 @default.
- W1418803502 cites W2110725391 @default.
- W1418803502 cites W2114057741 @default.
- W1418803502 cites W2121721406 @default.
- W1418803502 cites W2122204228 @default.
- W1418803502 cites W2146322692 @default.
- W1418803502 cites W2147670444 @default.
- W1418803502 cites W2157864534 @default.
- W1418803502 cites W2158242553 @default.
- W1418803502 cites W2169068835 @default.
- W1418803502 cites W2171439440 @default.
- W1418803502 cites W2321702846 @default.
- W1418803502 cites W2331558852 @default.
- W1418803502 cites W2949202148 @default.
- W1418803502 cites W2949634461 @default.
- W1418803502 cites W2950676875 @default.
- W1418803502 cites W2951009600 @default.
- W1418803502 cites W2951655110 @default.
- W1418803502 cites W2952770728 @default.
- W1418803502 cites W3004533583 @default.
- W1418803502 cites W3004745603 @default.
- W1418803502 cites W3005058788 @default.
- W1418803502 cites W3005416623 @default.
- W1418803502 cites W3137631532 @default.
- W1418803502 cites W4230177370 @default.
- W1418803502 cites W4231410391 @default.
- W1418803502 cites W4235931429 @default.
- W1418803502 cites W4244345437 @default.
- W1418803502 cites W4250756455 @default.