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- W1419956502 abstract "Because of their dynamic nature, stimuli-responsive molecules that undergo conformational changes have attracted much research interest for applications in the field of actuators and sensors. In particular, redox-active molecules that undergo redox state switching have many advantages, including electrical control and drastic conformational change that involves electrostatic interactions. In this review, we focus on the conformational changes for macromolecularly and molecularly assembled systems and evaluated their potential for use as building blocks of redox-driven soft actuators. Moreover, the current review provides insights for the design and fabrication of actuating materials by considering changes in redox state. This review focuses on redox-induced molecular actuation in macromolecular and self-assembled systems. Effective amplifications of conformational changes of unit molecular part are explored on the basis of three categories: polymeric system; molecular interactions; and self-assembled system. The importance of highly ordered structures is suggested to effectively amplify conformational change of small molecular unit into macroscopic deformation of bulk materials. Finally, future outlook toward electrochemical soft actuators and tips to prepare stimuli-responsive molecular assemblies, which undergo amplification in conformational change of constituent molecules, are provided." @default.
- W1419956502 created "2016-06-24" @default.
- W1419956502 creator A5003772979 @default.
- W1419956502 creator A5090296062 @default.
- W1419956502 date "2015-09-09" @default.
- W1419956502 modified "2023-09-27" @default.
- W1419956502 title "Redox-induced actuation in macromolecular and self-assembled systems" @default.
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