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- W142052565 abstract "Abstract The valence state of Co ions in Pr 1− x Ca x CoO 3− δ and Pr 1− x Sr x CoO 3− δ has been investigated by an analysis of the Co-L 3 X-ray absorption near-edge structure (XANES) profile. The observed intensity distributions of Co-L 3 XANES change continuously with increasing concentration of alkaline-earth ions. To investigate the origin of this change in the XANES profile, charge transfer multiplet calculations were carried out, which could successfully explain the change in the spectral profile; they also suggest that the valence state of Co ions in Pr 1− x Ca x CoO 3− δ and Pr 1− x Sr x CoO 3− δ is between 3+ and 4+ and increases gradually with the concentration of alkaline-earth ions." @default.
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- W142052565 date "2012-11-01" @default.
- W142052565 modified "2023-10-01" @default.
- W142052565 title "Co-L3 X-ray absorption near-edge structure analysis of Pr1−xCaxCoO3−δ and Pr1−xSrxCoO3−δ" @default.
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- W142052565 doi "https://doi.org/10.1016/j.physb.2012.06.029" @default.
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