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• W1421302377 endingPage "59" @default.
• W1421302377 startingPage "1" @default.
• W1421302377 abstract "In atomic spectra, the principal factor determining the fine structure is the coupling between the spin and orbital motion of the electrons. This coupling can be interpreted as the energy of the spin magnetic moment of the electron in the magnetic field produced by its own orbital motion. There are two classes of molecule for which spin–orbit coupling can be considered in the same way as for atoms. The first of these consists of the diatomic molecules. Their axial symmetry cannot be removed by a motion of the nuclei, and, therefore, they retain one component of angular momentum as a constant of the motion along with the possibility of doubly degenerate states. The other class of molecules, whose spin–orbit effects may be as large as for atoms, consists of the complexes formed between a central heavy atom or ion and some surrounding ligands. The binding of these complexes is often such that the electrons on the central ion retain much of their atomic character." @default.
• W1421302377 created "2016-06-24" @default.
• W1421302377 creator A5047687509 @default.
• W1421302377 creator A5068965408 @default.
• W1421302377 date "1965-01-01" @default.
• W1421302377 modified "2023-09-23" @default.
• W1421302377 title "Molecular Orbital Theory of the Spin Properties of Conjugated Molecules" @default.
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