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- W1425094137 abstract "I herein describe iridium- and rhodium-catalyzed C(sp3)-H silylation at the benzylic position and the position adjacent to a nitrogen atom by the aid of a nitrogen directing group. The silylated products could be further carboxylated with carbon dioxide (1 atm of CO2) under fluoride-mediated conditions, giving carboxylic acid derivatives in high yields. It should be a formal carboxylation of C(sp3)-H bonds triggered by metal-catalyzed C-H silylation. We also developed a novel triborylation reaction of terminal C(sp3)-H bonds (2-ethylpyridine derivatives). The obtained triborylated compounds were successfully converted into carboxylic acids by using either CsF under a CO2 atmosphere or H2O2 in the presence of TsOH·H2O." @default.
- W1425094137 created "2016-06-24" @default.
- W1425094137 creator A5035949922 @default.
- W1425094137 date "2015-01-01" @default.
- W1425094137 modified "2023-10-16" @default.
- W1425094137 title "Development of Catalytic C(sp<sup>3</sup>)-H Silylation and Triborylation Followed by Carboxylation with CO<sub>2</sub>" @default.
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- W1425094137 doi "https://doi.org/10.5059/yukigoseikyokaishi.73.810" @default.
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