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- W1425322399 endingPage "3716" @default.
- W1425322399 startingPage "3704" @default.
- W1425322399 abstract "The mechanism of the N-alkylation of amines with alcohols catalyzed by an iridium complex containing an N-heterocyclic carbene (NHC) ligand with a tethered alcohol/alkoxide functionality was investigated by a combination of experimental and computational methods. The catalyst resting state is an iridium–hydride species containing the amine substrate as a ligand, and decoordination of the amine, followed by coordination of the imine intermediate to the iridium center, constitute the rate-determining step (rds) of the catalytic process. The alcohol/alkoxide that is tethered to the NHC participates in every step of the catalytic cycle by accepting or releasing protons and forming hydrogen bonds with the reacting species. Thus, the iridium complex with the alcohol/alkoxide tethered to the N-heterocyclic carbene ligand acts as a bifunctional catalyst." @default.
- W1425322399 created "2016-06-24" @default.
- W1425322399 creator A5007498431 @default.
- W1425322399 creator A5042104271 @default.
- W1425322399 creator A5047606277 @default.
- W1425322399 creator A5048181811 @default.
- W1425322399 creator A5064227054 @default.
- W1425322399 date "2015-05-20" @default.
- W1425322399 modified "2023-10-17" @default.
- W1425322399 title "Mechanistic Studies on the Alkylation of Amines with Alcohols Catalyzed by a Bifunctional Iridium Complex" @default.
- W1425322399 cites W1963936702 @default.
- W1425322399 cites W1965435179 @default.
- W1425322399 cites W1966182479 @default.
- W1425322399 cites W1967386369 @default.
- W1425322399 cites W1969823780 @default.
- W1425322399 cites W1972542737 @default.
- W1425322399 cites W1972768193 @default.
- W1425322399 cites W1972957600 @default.
- W1425322399 cites W1977420451 @default.
- W1425322399 cites W1979259658 @default.
- W1425322399 cites W1980865343 @default.
- W1425322399 cites W1982356449 @default.
- W1425322399 cites W1984237201 @default.
- W1425322399 cites W1986674427 @default.
- W1425322399 cites W1989177683 @default.
- W1425322399 cites W1991670056 @default.
- W1425322399 cites W2001282294 @default.
- W1425322399 cites W2002324876 @default.
- W1425322399 cites W2003005741 @default.
- W1425322399 cites W2003105464 @default.
- W1425322399 cites W2005085615 @default.
- W1425322399 cites W2005244766 @default.
- W1425322399 cites W2005844093 @default.
- W1425322399 cites W2007508812 @default.
- W1425322399 cites W2008217902 @default.
- W1425322399 cites W2008442341 @default.
- W1425322399 cites W2008477575 @default.
- W1425322399 cites W2008959965 @default.
- W1425322399 cites W2011711747 @default.
- W1425322399 cites W2011814830 @default.
- W1425322399 cites W2011906026 @default.
- W1425322399 cites W2013093875 @default.
- W1425322399 cites W2014877194 @default.
- W1425322399 cites W2016913594 @default.
- W1425322399 cites W2017610712 @default.
- W1425322399 cites W2018014134 @default.
- W1425322399 cites W2018097469 @default.
- W1425322399 cites W2018241005 @default.
- W1425322399 cites W2022629246 @default.
- W1425322399 cites W2023271753 @default.
- W1425322399 cites W2028257896 @default.
- W1425322399 cites W2028851759 @default.
- W1425322399 cites W2030795020 @default.
- W1425322399 cites W2031003047 @default.
- W1425322399 cites W2032708088 @default.
- W1425322399 cites W2033288172 @default.
- W1425322399 cites W2033556576 @default.
- W1425322399 cites W2034821253 @default.
- W1425322399 cites W2034925175 @default.
- W1425322399 cites W2035867131 @default.
- W1425322399 cites W2037796103 @default.
- W1425322399 cites W2038696941 @default.
- W1425322399 cites W2038961860 @default.
- W1425322399 cites W2043713221 @default.
- W1425322399 cites W2045757382 @default.
- W1425322399 cites W2048452974 @default.
- W1425322399 cites W2050828896 @default.
- W1425322399 cites W2052243012 @default.
- W1425322399 cites W2057144214 @default.
- W1425322399 cites W2058178774 @default.
- W1425322399 cites W2060767646 @default.
- W1425322399 cites W2064280767 @default.
- W1425322399 cites W2065176306 @default.
- W1425322399 cites W2067338689 @default.
- W1425322399 cites W2070822768 @default.
- W1425322399 cites W2073637781 @default.
- W1425322399 cites W2076336288 @default.
- W1425322399 cites W2079442392 @default.
- W1425322399 cites W2080299113 @default.
- W1425322399 cites W2081236496 @default.
- W1425322399 cites W2081943985 @default.
- W1425322399 cites W2082184720 @default.
- W1425322399 cites W2082325844 @default.
- W1425322399 cites W2082614543 @default.
- W1425322399 cites W2082726452 @default.
- W1425322399 cites W2082965050 @default.
- W1425322399 cites W2083611854 @default.
- W1425322399 cites W2084616510 @default.
- W1425322399 cites W2085336624 @default.
- W1425322399 cites W2085595472 @default.
- W1425322399 cites W2086492638 @default.
- W1425322399 cites W2090795043 @default.
- W1425322399 cites W2091067362 @default.
- W1425322399 cites W2092816490 @default.
- W1425322399 cites W2097743599 @default.
- W1425322399 cites W2100456449 @default.
- W1425322399 cites W2115653136 @default.
- W1425322399 cites W2115861729 @default.