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- W142946907 abstract "The calculation indicate that the polarity of the C=C bond in vinylidenephosphonic acid is reversed on complete ionization, which corresponds to the observed change in the disposition of the carbon-atom signals in the /sup 13/C NMR spectra for the acid and tetraanion. When vinylphosphonic acid and other ..cap alpha..,..beta..-unsaturated monophosphonic acids are ionized completely (in the formation of the dianions and monoanions), the /sup 13/C NMR spectra show the C/sub ..cap alpha../ signal shifting to the weak-field side and C/sub ..beta../ to the strong one, but there is no change in the mutual disposition of the signals, while the calculations indicate that there is no change in the polarity of the C=C bond." @default.
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- W142946907 date "1987-08-20" @default.
- W142946907 modified "2023-09-27" @default.
- W142946907 title "Electronic structures of vinylidenediphosphonic acid and related compounds" @default.
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